These two are not interchangeable and maybe slightly misinterpreted at times. With that out of the way, is it possible to achieve a reflective shine on a surface when the diffuse alpha is not present in the model and all you have are the bumps and specs? Just to be very specific, reflective shine is basically the ability to see my reflection in the surface. Sheen, on the other hand is what I see right now using just bumps and specs. . .a soft luster that picks up the light as you move around the surface. . .no reflection.
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